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3 year ago
MAB series WAlB Black powder
The X element in MXenes has been extended to include boron, and this series of materials has been named MBenes. The theoretical results of Sun Zhimei et al. show that two-dimensional Mo2B2 and Fe2B2 can be prepared by etching the MAB phase of the block precursor with HF acidification. These two MBene have high stability, high Young's modulus and excellent electronic conductivity, and have small diffusion coefficient and high storage capacity after adsorbing lithium/sodium ions. It is a kind of anode material with potential application value for lithium/sodium ion batteries.
Alameda et al. performed local chemical separation of Al from MoAlB single crystals and reacted with NaOH solution at room temperature to generate multiple metastable Mo-Al-B co-symbiont phases. Two-dimensional monolayer MoB (MBene) was observed in these metastable co-biont phases. Nillson s. protein-based team combined with density functional theory and the crystal structure prediction technology reported that a two-dimensional six-party Zr2B2, its good gold properties, stability, and electrical conductivity, based on the preparation of lithium ion battery Zr2B2 diffusion coefficient is very low, and the theoretical specific capacity is greater than the industrial use of graphite electrode, is a good lithium ion battery anode material.
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